Attends, euh, là, c'est léger.
merci de donner l'intégralité du log de ton serveur pour ce refus, ce que ça donne en envoi depuis le serveur, etc
bref, décris ton problème stp, ainsi que la configuration, tout le fatras
à vue de groin, il te manque un truc (en l'occurrence soit ton domaine soit l'IP de la machine qui tourne outlook) dans la zone suivante de ton main.cf (tu l'as lu attentivement? je t'ai dit ici même et sur fcms qu'il fallit bien le lire ainsi que les sample)
# TRUST AND RELAY CONTROL
# The mynetworks parameter specifies the list of "trusted" SMTP
# clients that have more privileges than "strangers".
#
# In particular, "trusted" SMTP clients are allowed to relay mail
# through Postfix. See the smtpd_recipient_restrictions parameter
# in file sample-smtpd.cf.
#
# You can specify the list of "trusted" network addresses by hand
# or you can let Postfix do it for you (which is the default).
#
# By default (mynetworks_style = subnet), Postfix "trusts" SMTP
# clients in the same IP subnetworks as the local machine.
# On Linux, this does works correctly only with interfaces specified
# with the "ifconfig" command.
#
# Specify "mynetworks_style = class" when Postfix should "trust" SMTP
# clients in the same IP class A/B/C networks as the local machine.
# Don't do this with a dialup site - it would cause Postfix to "trust"
# your entire provider's network. Instead, specify an explicit
# mynetworks list by hand, as described below.
#
# Specify "mynetworks_style = host" when Postfix should "trust"
# only the local machine.
#
#mynetworks_style = class
#mynetworks_style = subnet
#mynetworks_style = host
# Alternatively, you can specify the mynetworks list by hand, in
# which case Postfix ignores the mynetworks_style setting.
#
# Specify an explicit list of network/netmask patterns, where the
# mask specifies the number of bits in the network part of a host
# address.
#
# You can also specify the absolute pathname of a pattern file instead
# of listing the patterns here. Specify type:table for table-based lookups
# (the value on the table right-hand side is not used).
#
#mynetworks = 168.100.189.0/28, 127.0.0.0/8
#mynetworks = $config_directory/mynetworks
#mynetworks = hash:/etc/postfix/network_table
mynetworks = 127.0.0.0/8